收藏本站
收藏 | 投稿 | 论文排版

A New One-dimensional Complex Assembled by 4-Nitrobenzoic Acid and Bis(imidazol) Ligands:Syntheses, Structures and Theoretical Calculations

李秀梅  潘亚茹  刘博  周实  常鹰飞  
【摘要】:A new Zn(Ⅱ)coordination polymer,[Zn(nba)_2(mbix)]_(2n)(1,Hnba=4-nitrobenzoic acid,mbix=1,3-bis(imidazol-1-ylmethyl)-benzene),was synthesized and characterized by elemental analyses,IR spectra,TG,fluorescence spectroscopy,single-crystal and powder X-ray diffractions.It belongs to the triclinic system,■ space group,with a=9.341(2),b=13.029(3),c=23.660(6)?,α=99.603(6)°,β=90.461(6)°,γ=90.597(5)°,V=2838.9(12)?~3 and Z=2.It shows one-dimensional chains which are further linked by C–H···O hydrogen bonds andπ-πstacking interactions to yield a three-dimensional supramolecular structure.In addition,the Natural Bond Orbital(NBO)was analyzed in using the PBE0/LANL2DZ method built in Gaussian 09 Program.The calculation results indicated obvious covalent interaction between the coordinated atoms and Zn(Ⅱ)ion.

知网文化
【相似文献】
中国期刊全文数据库 前20条
1 李秀梅;潘亚茹;刘博;周实;常鹰飞;;A New One-dimensional Complex Assembled by 4-Nitrobenzoic Acid and Bis(imidazol) Ligands:Syntheses, Structures and Theoretical Calculations[J];Chinese Journal of Structural Chemistry;2019年05期
2 王庆伟;孙铭;王亚男;齐晓飞;李秀梅;刘博;;Synthesis, Crystal Structure and Theoretical Calculations of a New Two-dimensional Co(Ⅱ) Coordination Polymer Based on Oxalic Acid and Bis(imidazol) Ligands[J];结构化学;2015年03期
3 LI Xiu-Mei;SUN Ming;PAN Ya-Ru;JI Jian-Ye;;Synthesis, Crystal Structure and Theoretical Calculations of a New Co(Ⅱ) Coordination Polymer Based on 5-Nitroisophthalic Acid and Bis(imidazol) Ligands[J];结构化学;2016年02期
4 王蕾;倪良;黄艳菊;姚加;;Synthesis,Structure,Fluorescent Property and Natural Bond Orbital(NBO) Analysis of a One-dimensional Cobalt(III) Complex Containing 1,3-Benzenedicarboxylate and 2-Methyldipyrido[3,2-f:2',3'-h]quinoxaline Ligand[J];结构化学;2012年05期
5 朱美安;郭星哲;肖丽;陈水生;;A New Cd(Ⅱ) Coordination Compound Based on 4-(1,2,4-Triazol-4-yl)phenylacetic Acid:Synthesis,Structure and Photoluminescence Property[J];结构化学;2018年03期
6 黄艳菊;倪良;朱彦煜;姚加;;Hydrothermal Processing,Characterization and Theoretical Calculations of a Copper(Ⅱ) Compound with 1,10-Phenanthroline Derivative Ligand:2-(4-Methoxyphenyl)-1H-imidazo[4,5-f][1,10] Phenanthroline[J];结构化学;2012年03期
7 ;Synthesis and Crystal structure of Poly{[Co(4,4'-bpy)(H_2O)_4]SO_(4·)(4-abaH)_(2·)3H_2O}[J];结构化学;2005年02期
8 王秀艳;高文昱;周筱绗;刘东雪;胡波;孔治国;;A New Manganese(Ⅱ) Coordination Compound Constructed by 1,10-Phenanthroline Derivative and Chlorine Anions: Synthesis, Crystal Structure and Theoretical Calculation[J];Chinese Journal of Structural Chemistry;2019年05期
9 Xiong-Fei Li;Shang-Bo Yu;Bo Yang;Jia Tian;Hui Wang;Dan-Wei Zhang;Yi Liu;Zhan-Ting Li;;A stable metal-covalent-supramolecular organic framework hybrid: enrichment of catalysts for visible light-induced hydrogen production[J];Science China(Chemistry);2018年07期
10 余友谊;陈建新;柯志聪;胡丽姗;余颖华;林欣蓉;张治纯;;Hydrothermal Synthesis,Crystal Structure and Characterization of a New Keggin Polyoxometalate {[Ag~I(4,4’-bipy)]_3[PW_(12)O_(40)]}·(4,4’-bipy)[J];结构化学;2011年03期
11 ;Theoretical Study on the Molecular Orbital and Stabilization Energy of Substituted Lithium Carbene Cations[J];Chinese Chemical Letters;1998年04期
12 ;Supramolecular gel:From structure to function[J];Chinese Science Bulletin;2012年33期
13 刘新征;范黎明;孙忠;张伟;丁元帅;张修堂;;Synthesis, Structure, and Luminescence of a New Nickel(Ⅱ) Coordination Polymer Based on 2,6-Bis(4'-carboxyphenyl)-4-phenylpyridine[J];结构化学;2013年07期
14 才华;郭英;栗建刚;吴瑶;;Novel Copper(II) and Zinc(II) 2-D Supramolecular Structures Based on Carboxylate and 1-Substitutedimidazole Mixed-ligands[J];结构化学;2011年11期
15 高竹青;李红晋;M.Kirillov Alexander;顾金忠;;Syntheses, Crystal Structures and Magnetic Properties of Cobalt(Ⅱ) and Manganese(Ⅱ) Coordination Polymers Constructed from 5-(Pyridin-4-yl)Isophthalate Ligands[J];结构化学;2014年04期
16 王克栋;段坤杰;刘玉芳;;Methyl orbital signatures in 2-amino-1-propanol[J];Chinese Physics B;2012年07期
17 陈水生;乔瑞;盛良全;杨松;;A New Three-dimensional Supramolecular Polymer Built from Non-covalent Bonding Interactions[J];结构化学;2014年04期
18 邹华红;桂柳成;李海叶;文长春;胡坤;程蕾;黄富平;;Synthesis,Crystal Structure and Luminescent Properties of a Nd(Ⅲ) Complex Constructed from 2-Pyridyl-4,5-imidazoledicarboxylic Acid[J];结构化学;2012年04期
19 Lada Puntus;Konstantin Lyssenko;;Influence of non-covalent interactions on properties of lanthanide systems with aromatic ligands[J];Journal of Rare Earths;2008年02期
20 ;Synthesis, Crystal Structure and Characterization of a One-dimensional Supramolecular Rare Earth Complex of N-(6-(4-Methylpyridinyl))ketoacetamide[J];结构化学;2007年08期
中国重要会议论文全文数据库 前10条
1 Yan Alexander Wang;;Recovering Band Structure and Orbital Information from Orbital-Free Density Functional Theory[A];中国化学会第九届全国量子化学学术会议暨庆祝徐光宪教授从教六十年论文摘要集[C];2005年
2 SHAO Guang-Kui;ZHAO Mei;LV Jing;GUO Dian-Shun;;Novel optical and electrochemical active receptors generated via Ugi four-component reaction for selective sensing of Cu~(2+)[A];中国化学会第九届全国有机化学学术会议论文摘要集(5)[C];2015年
3 房鹏金;曲胜男;胡鹏宇;张慧珍;周成合;;Synthesis of Novel Sulfonamide-based Polymers and Antimicrobial activity[A];全国第十八届大环化学暨第十届超分子化学学术讨论会会议论文集(下)[C];2016年
4 ;A significant reminder for organic photovoltaic materials based on the natural bond orbital analyses of antipyrine derivatives[A];中国化学会第27届学术年会第05分会场摘要集[C];2010年
5 魏现奎;邹涛;王芬;;Cross-controlled magnetoelectric effects at room temperature in magnetic ion doped ferroelectrics[A];2011中国材料研讨会论文摘要集[C];2011年
6 ;Mass spectrometric study on inorganic-organic hybrid supramolecular metal oxides[A];第六届全国物理无机化学会议论文摘要集[C];2012年
7 Warren J.Hehre;;PM3(TM): Extension of the PM3 formalism to d orbital and optimization of parameters for all transition metals[A];中国化学会第九届全国量子化学学术会议暨庆祝徐光宪教授从教六十年论文摘要集[C];2005年
8 Xin Chen;Wanlu Li;Yafan Zhao;Jun Li;;Global Minimum Search of Boron Metallic Clusters[A];第七届全国物理无机化学学术会议论文集[C];2016年
9 陈澜;奚成钢;祁琪;王辉;周亚明;张丹维;黎占亭;;Protonation-induced switching of pleated foldamers of diaminonaphtanalene-bipyridinium alternating dynamic covalent polymers[A];中国化学会第九届全国有机化学学术会议论文摘要集(5)[C];2015年
10 Teng Ben;Shilun Qiu;;FABRICATION OF COF-MOF COMPOSITE MEMBRANES[A];中国晶体学会第六届学术年会暨会员代表大会(功能分子晶体分会)论文摘要集[C];2016年
 快捷付款方式  订购知网充值卡  订购热线  帮助中心
  • 400-819-9993
  • 010-62982499
  • 010-62783978