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Stable Isotopes and Halogen Geochemistry of the Huayuan Carbonate-hosted Pb-Zn Ore District, South China: Implications for the Salt Source of Ore-forming Fluids

YANG Zhen  JIANG Mengjie  ZHAO Shaorui  DING Zhenju  HE Mouchun  
【摘要】:The Huayuan Pb-Zn ore district in China, located in western Hunan Province, is a giant carbonate-hosted Pb-Zn ore district. The source of ore-forming brines in this ore district remains poorly constrained. Whether the highly saline brines are derived from evaporated seawater or dissolved evaporates continues to be intensely debated. Carbonate minerals associated with Pb-Zn mineralization have δ~(13)CV-PDB and δ~(18)OV-SMOW values ranging from-5.55‰ to +1.35‰(mean value of-0.69‰; n = 14) and +16.28‰ to +25.05‰(mean value of +20.22‰; n = 14), respectively. This indicates that carbonate minerals are dominantly formed from dissolved ore-hosted carbonate rocks. The δ~(34)S values of sulfides range from +20.2‰ to +36.8‰, with an average value of +30.0‰(n = 27). These results suggest that sulfur is predominantly derived from the thermochemical sulfate reduction of marine sulfate. The crush-leach analyzed solute data of fluid inclusions in sphalerite show the ore-forming fluids have Cl/Br molar ratios range from 118 to 384, and Na/Br molar ratios from 39 to 160(n = 8). These Cl/Br ratios of hydrothermal fluid are much lower than those of seawater(657 to 564), but are consistent with bittern brines through early halite precipitation. We propose that ore-forming fluids are mainly derived from evaporitic basin brines, which leached base metals from the basement and/or country rocks. The brine then migrated to the basin margins through clastic rocks of basement and then precipitated sulfides by thermochemical sulfate reduction.

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5 ;Formation mechanism of carbonate cemented zones adjacent to the top overpressured surface in the central Junggar Basin,NW China[J];Science China(Earth Sciences);2010年04期
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12 Harry H. ROBERTS;;Petrographic and geochemical characterization of seep carbonate from Alaminos Canyon,Gulf of Mexico[J];Chinese Science Bulletin;2008年11期
13 高岗 ,郝石生 ,王晖;Characteristics of hydrocarbon generation and expulsion in matrix and stylolite of carbonate rocks[J];Science in China(Series D:Earth Sciences);1999年02期
14 王兆云,范璞,程克明;The thermal evolution indicator of carbonate rocks[J];Science in China,Ser.B;1995年06期
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19 ZHENG Ping;WANG Lansheng;YANG Yi;GAO Xi;ZHANG Zhonghua;;Analysis of carbon and oxygen stable isotopes in carbonate rocks by the laser micro-sampling technique[J];Chinese Journal of Geochemistry;2013年02期
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