Synthesis,Crystal Structure,DFT Studies and Biological Activity of a Novel Schiff Base Containing Triazolo[4,3-a]pyridine Moiety

【摘要】：The novel Schiff base(E)-8-chloro-N?-(4-(dimethylamino)benzylidene)-[1,2,4]triazolo[4,3-a]pyridine-3-carbohydrazide was synthesized and characterized by ~1H NMR,MS,elemental analysis and X-ray diffraction.The compound crystallizes in the monoclinic space group P2_1/c with a = 7.091(2),b = 10.750(3),c = 21.380(6) ?,β = 96.299(6)°,V = 1619.7(8) ?~3,Z = 4 and R = 0.0351.Theoretical calculation of the title compound was carried out with the B3LYP/6-31 G basis set.The frontier orbital energy and atomic net charges were discussed.It is found that the experimental data show good agreement with the calculated values.And the compound exhibits good antifungal activity against Stemphylium lycopersici(Enjoji) Yamamoto.

下载App查看全文

下载全文更多同类文献

PDF全文下载

CAJ全文下载

(如何获取全文？欢迎：购买知网充值卡、在线充值、在线咨询)

CAJViewer阅读器支持CAJ、PDF文件格式，AdobeReader仅支持PDF格式

	【相似文献】
	【相似文献】

中国期刊全文数据库

前20条

1	;Theoretical Studies on Electronic Spectrum Property of 2-(2-Hydroxyphenyl)pyridine Via Time-dependence Density Functional Theory Method[J];Chemical Research in Chinese Universities;2003年02期
2	Takeko MATSUMURA-INOUE;Microwave Synthesis, Characterization and DNA-binding Properties of a New Cobalt(Ⅱ) Complex with 2,6-Bis(benzimidazol-2-yl)pyridine[J];Chinese Chemical Letters;2004年06期
3	;A Study on Phase States of the Catalytic System of FeCl_3-Al(i-Bu)_3-pyridine[J];Petroleum Science;2006年01期
4	;Hydrothermal Synthesis,Crystal Structure and Thermal Analysis of a Dinuclear Complex Cd_2(3,5-Dinitrobenzoate)_4(pyridine)_4[J];结构化学;2006年11期
5	;A novel synthesis of pyrazolo[3,4-b]pyridine derivatives through multi-component reaction in ionic liquid[J];Chinese Chemical Letters;2008年02期
6	;Synthesis and activity evaluation of some novel derivatives of 4,5,6,7-tetrahydrothieno [3,2-c]-pyridine[J];Chinese Chemical Letters;2008年06期
7	李爱科;陈建新;张文杰;朱美平;张力;林欣蓉;;Synthesis and Crystal Structure of 2,6-Bis(benzimidazo(1,2-c)-quinazolin-6-yl)pyridine Tetrahydrate[J];结构化学;2009年03期
8	;Recognition of amino acids and anions by a Zn(Ⅱ)-methylazacalix[4]pyridine complex[J];Science in China(Series B:Chemistry);2009年10期
9	;STUDY ON THE REACTION OF ACYLISOCYANATE AND ARYL UREA[J];Chinese Chemical Letters;1992年07期
10	;A Study of Acidic Sites in H[M]-ZSM-5 Zeolites by XPS, IR and TPD[J];Chemical Research in Chinese Universities;1992年04期
11	;A New Method for the Preparation of Substituted Benzil Compounds from Substituted Benzoin Compounds[J];厦门大学学报(自然科学版);1999年S1期
12	;Study on Separation of Benzophenobarbital and Dibenzophenobarbital[J];厦门大学学报(自然科学版);1999年S1期
13	郭倩玲,朱文祥,郭蓉,延玺,王如骥;Crystal Structure of Complex Tris(4,4,4-trifluoro-1-phenyl-1,3-butanedione)(1,10-phenanthroline) Europium(III)[J];Chinese Journal of Chemistry;2003年02期
14	王锡森,宋玉梅,熊仁根;[Zn(sulfasalazine)_2(pyridine)][J];无机化学学报;2005年08期
15	;Synthesis and Characterization of Polyamide-Containing 2, 6-(Substituded) pyridine Derivatives[J];Wuhan University Journal of Natural Sciences;2006年03期
16	龙泽荣;赵启龙;李少光;夏娅娜;吴彪;;A New Diiminopyridyl Cobalt Complex [CoCl_2L](L=2,6-Bis(N,N'-bis(2,6-diisopropyl-4-(2,3-dimethyoxylbenzoylamide)phenylimino))pyridine)[J];结构化学;2010年06期
17	薛奇;江善根;;A FOURIER TRANSFORM INFRARED SPECTROSCOPIC STUDY OF THE REACTION BETWEEN POLY (VINYL PYRIDINE)S AND EPOXY COMPOUNDS[J];Chinese Journal of Polymer Science;1987年02期
18	Therese M.COTTON;;PROMOTION EFFECT OF PYRIDINE FOR THE DIRECT ELECTROCHEMISTRY OF CYTOCHROME C AT GOLD ELECTRODES[J];Chinese Chemical Letters;1992年02期
19	;Synthesis of 1-acyl-5-aryl biurets[J];Chinese Journal of Chemistry;1995年04期
20	;Hydrothermal Synthesis and Structure Characterization of Compound Zn(Hpydc)_2(H_2O) (pydc=pyridine-2,5-dicarboxylate)[J];结构化学;2001年06期

中国重要会议论文全文数据库

前10条

1	;Hydrothermal Synthesis and Structure of [Zn_4(pdc)_4(H_2O)_(10)](pdc=pyridine-2,5-dicarboxylate)[A];大环化学和超分子化学研究进展——中国化学会全国第十二届大环第四届超分子化学学术讨论会论文集[C];2004年
2	;INSTITUTE OF MULTIPURPOSE UTILIZATION OF MINERAL RESOURCES——PUBLICATIONS[A];中国地质科学院文集（1983中英文合订本）[C];1983年
3	;Design and Synthesis of Pyridine-derived Bis-nitrogen Mustard[A];有机合成创新—产业化的新动力——中国化学会全国第三届有机合成化学与过程学术讨论会论文摘要集[C];2010年
4	;Study on the Mechanism of a Novel Tandem Reaction to Produce Substituted lmidazo[1,5-a]pyridine Derivatives[A];中国化学会第四届有机化学学术会议论文集（下册）[C];2005年
5	;9-A Powerful Strategy for Synthesis of Fe-Complexes with in situ Generated Substituted 1-Pyridineimidazo-[1,5-a]pyridine Ligands[A];中国化学会第六届全国结构化学学术会议论文摘要[C];2012年
6	;Hydrothermal Synthesis and Crystal Structure of a 3D Open-framework Zincophosphate (C_4N_3H_(16))Zn_(4.5)(PO_4)_4[A];中国化学会第五届全国结构化学学术会议论文摘要集[C];2007年
7	;Synthesis,crystal structure and luminescent properties of a new 2D coordination polymer constructed by Mn(Ⅱ) with pyridine-3,4-dicarboxylate and 2,2’-bipyridine[A];中国化学会第五届全国结构化学学术会议论文摘要集[C];2007年
8	;Crystal Structure of the Inclusion Complex of Tetramethylcucurbit[6]uril with 3-(aminomethyl)pyridine HCl Salt[A];全国第十四届大环化学暨第六届超分子化学学术讨论会论文专辑[C];2008年
9	;Synthesis,Crystal Structure and Properties of A 3D Holmium(Ⅲ) Coordination Framework with Pyridine 2,6-dicarboxylate and Oxalate[A];大环化学和超分子化学的新发展——当前学科交叉的一个重要桥梁——中国化学会全国第十五届大环化学暨第七届超分子化学学术讨论会论文摘要集[C];2010年
10	;3D Terbium Framework Exhibiting Luminescent Increase upon Dehydration[A];第六届全国物理无机化学会议论文摘要集[C];2012年

	快捷付款方式		订购知网充值卡	订购热线	帮助中心
	微信支付支付宝银行卡	知网卡在线购卡更多>>	免费送卡上门银行汇款购卡邮局汇款购卡	400-819-9993 010-62982499 010-62783978	常见问题在线咨询阅读器下载	充值中心知网卡新手指南