收藏本站
《结构化学》 2007年10期
收藏 | 投稿 | 手机打开
二维码
手机客户端打开本文

Synthesis and Crystal Structur of (4,4′-H_2bipy)[CdBr_4]·H_2O

陈文通  郭国聪  曾锡瑞  李新发  方小牛  匡汉茂  刘冬生  刘利民  
【摘要】:The title compound (4,4′-H2bipy)[CdBr4]·H2O 1 has been synthesized via hydrothermal reaction and characterized by X-ray diffraction. The crystal belongs to monoclinic,space group P21/c with a=8.260(3),b=23.926(7),c=9.774(2),β=106.777(9)o,C10H12Br4CdN2O,Mr=608.26,V=1849.4(9)3,Z=4,Dc=2.185 g/cm3,S=1.005,μ(MoKα) =9.814 mm–1,F(000)=1128,R=0.0646 and wR=0.0989. The crystal structure analysis of 1 reveals that the title compound features an isolated structure,based on discrete 4,4′-H2bipy moieties and lattice water molecules which are linked by hydrogen bonds together with tetra-hedral cadmium atoms terminally coordinated by four bromine atoms.
【作者单位】College
【基金】:the doctor scientific research start-up foundation of Jinggangshan University, China
【分类号】:O621.1

免费申请
中国知网广告投放
 快捷付款方式  订购知网充值卡  订购热线  帮助中心
  • 400-819-9993
  • 010-62791813
  • 010-62985026